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Registros recuperados: 32
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Boundary conditions for heavy metals at the air-sea interface OMA
Dehairs, F.A.; Dedeurwaerder, H.; Dejonghe, M.; Decadt, G.; Gillain, G.; Baeyens, W.F.J.; Elskens, I..
During 1980 and 1981 the aerosol burden as well as the wet and dry atmospheric fall-out of Cu, Cd, Pb, Zn, Fe and Mn to the sea have been studied in the Belgian coastal area. Atmospheric Cu, Zn and Cd are observed to be introduced into the sea mainly by wet fall-out, while Fe, Mn and also Pb have a dry and wet fall-out of similar magnitude. Of these elements, Cu, Zn and Cd have the highest washout factors. Furthermore, for all elements, excepted Mn, discrepancies exist between washout factors above land and sea, with values up to 5 times larger above the sea.On the scale of the North Sea, atmospheric fall-out of Cu, Zn, Pb and Cd exceeds by one order of magnitude the combined input of the rivers Scheldt, Rhine and Meuse, while fall-out of Fe and Mn is of...
Tipo: Info:eu-repo/semantics/article
Ano: 1982 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=10065
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Distribution, transport and fate of Bi, Cu, Cd, Hg, Pb, Sb and Zn in the Belgian coastal marine environment. Part IV: The river Scheldt as a transport route of heavy metals to the sea OMA
Baeyens, W.F.J.; Wartel, S.; Dehairs, F.A.; Decadt, G.; Bogaert, M.; Gillain, G.; Dedeurwaerder, H..
Tipo: Info:eu-repo/semantics/article
Ano: 1982 URL: http://www.vliz.be/imisdocs/publications/286409.pdf
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An automated method for the assessment of mercury adsorption rates on particulate suspended matter OMA
Baeyens, W.F.J.; Decadt, G.; Dehairs, F.A.; Goeyens, L..
A continuous filtration system connected to a mercury auto-analyzer has been constructed for obtaining mercury adsorption rates on particulate suspended matter. The capabilities of this device have been demonstrated by carrying out a series of experiments under controlled physicochemical parameter conditions on samples of the Scheldt estuary. Duplicate measurements showed coefficients of variation ranging from 1 to 6 %. Depending on the physico-chemical conditions, the initial adsorption rate per unit of dissolved mercury concentration varied between 1.2 and 8.1 x 10<sup>-2</sup> mn<sup>-1</sup>.
Tipo: Info:eu-repo/semantics/article Palavras-chave: Adsorption; Mercury; Methodology; Particulates; Suspended matter.
Ano: 1982 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3413
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Comparative study of different wet mineralisation digestion methods for the measurement of total mercury in biological samples OMA
Dehairs, F.A.; Decadt, G.; Baeyens, W.F.J..
Three botanical substrates and one milkpowder were mineralised and digested by the following methods in order to measure their total mercury content: (1) HF/HNO<sub>3</sub>-KMnO<sub>4</sub>; (2) H<sub>2</sub>SO<sub>4</sub>/HNO<sub>3</sub>-KMnO<sub>4</sub>; (3) H<sub>2</sub>SO<sub>4</sub>/HNO<sub>3</sub>- H<sub>2</sub>O<sub>2</sub>; (4) H<sub>2</sub>SO<sub>4</sub>/HNO<sub>3</sub>-UV irradiation/KMnO<sub>4</sub>; (5) H<sub>2</sub>SO<sub>4</sub>/HNO<sub>3</sub>/V<sub>2</sub>O<sub>5</sub>-catalyst...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Digestion; Mercury; Nutrients (mineral).
Ano: 1982 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3380
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Distribution, transport and fate of Bi, Cu, Cd, Hg, Pb, Sb and Zn in the Belgian coastal marine environment. Part V: Interaction kinetics between dissolved inorganic mercury and estuarine suspended matter OMA
Baeyens, W.F.J.; Decadt, G.; Dehairs, F.A.; Goeyens, L.; Dedeurwaerder, H.; Gillain, G..
Tipo: Info:eu-repo/semantics/article
Ano: 1982 URL: http://www.vliz.be/imisdocs/publications/286410.pdf
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Nitrogen cycling and budget in Belgian coastal waters: North Sea areas with and without river inputs OMA
Mommaerts, J.-P.; Pichot, G.; Ozer, J.; Adam, Y.A.; Baeyens, W.F.J..
The coastal sea off Belgium has been extensively studied for a number of years on a multidisciplinary basis. Thus the stocks within the system's various compartments as well as the carbon or nitrogen fluxes between them resulting from biological activity at several trophic levels have been measured. Further, the tidal and residual circulations have been investigated and modeled in addition to the erosive properties of the flow. There are strong differences between the more coastal part of this area and the open sea. In particular, inputs from rivers and channels seem to exert an influence beyond what could normally be expected in coastal areas.Adequate modelling of the nitrogen cycle in such a diverse environment demanded a fine approach, including a...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Nitrogen cycle River inflow ANE; Belgium; Belgian Coast ANE; North Sea; Southern Bight.
Ano: 1984 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3333
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Estimates of dry and wet deposition and resuspension fluxes of several trace metals in the Southern Bight of the North Sea OMA
Dedeurwaerder, H.L.; Dehairs, F.A.; Decadt, G.; Baeyens, W.F.J..
In this study we have investigated air-sea exchanges in the Belgian coastal area located in the Southern Bight of the North Sea. Since 1980 the tropospheric aerosol contents for the trace elements Cd, Cu, Mn, Pb, Zn and for the reference elements Al , Fe, Na have been monitored on an intermittent basis from a maritime sampling platform (Light-Vessel West-Hinder; position: 51°23.5'N- 2°21.5'E, fig. 1). During 1981 sampling campaigns at sea were paralleled by sampling campaigns on land, in the coastal area (natural reserve De Blankaert, located at 20 Km inland), in order to allow for a better evaluation of the specific source or sink role of the sea. No major source of pollution exists between the maritime and the continental sampling sites. During these...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Aeolian deposits Resuspension Trace metals ANE; North Sea; Southern Bight.
Ano: 1984 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3323
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Dynamic patterns of dissolved nitrogen in the Southern Bight of the North Sea OMA
Baeyens, W.F.J.; Mommaerts, J.-P.; Goeyens, L.; Dehairs, F.A.; Dedeurwaerder, H.; Decadt, G..
Spatial and temporal variations of dissolved inorganic nitrogen (DIN) have been assessed in onshore and offshore areas of the Southern Bight on the basis of several years' measurements. They indicate that both the residual flow lines and DIN isoconcentration lines run parallel with the coast except in the vicinity of important freshwater discharge points such as the Scheldt estuary. Evidence was found that the seasonal DIN oscillations are not created through fluctuations in input conditions at the lateral boundaries, despite considerable fluctuations in these inputs which include the English Channel (from 500 tons(t) N day<sup>-1</sup> in June up to approximately 2000 t N day<sup>-1</sup> in February) and also rivers such as the...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Dissolved organic nitrogen ANE; North Sea; Southern Bight.
Ano: 1984 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3310
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Preparation method for solid samples with low nitrogen content for spectrometric nitrogen-15 analysis OMA
Goeyens, L.G.; Stichelbaut, L.W.; Post, E.J.; Baeyens, W.F.J..
A new procedure for the conversion of bound nitrogen into nitrogen gas, applicable to solid material, is described. It embodies two main stages: the catalytic ammonification of the sample and the consecutive transformation of ammonium to molecular nitrogen by the modified Dumas method. The first step of the preparation is carried out in a quartz reactor, filled with granular nickel, at a temperature of 700°C, the ammonia gas produced being trapped in sulphuric acid. In the second step, this solution is neutralised, dried and subjected to the Dumas combustion.The addition of reagents does not influence the results of the measurements. Spectrometric <sup>15</sup>N percentage abundances are converted into mass spectrometric "true"...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Emission spectroscopy.
Ano: 1985 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3279
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Determination of methylmercury in biological samples by semiautomated headspace analysis OMA
Decadt, G.; Baeyens, W.F.J.; Bradley, D.; Goeyens, L..
Gas-liquid distribution coefficients of methylmercury halides dissolved in water or benzene have been assessed by using a headspace injection system coupled to a gas chromatograph-microwave-induced plasma system. Vapor concentrations decreased in the following order: CH<sub>3</sub>HgI > CH<sub>3</sub>HgBr > CH<sub>3</sub>HgCl. To transform all methylmercury iodide, iodoacetic acid (IAc) is used as the liberating agent. Methylmercury iodide degradation is prevented by the addition of sodium thiosulfate (0.05 M). The results obtained with internal standard addition are not influenced by other volatile compounds including other mercury compounds. The method has been applied to a series of biological samples. The...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Analytical techniques; Chemical analysis; Mercury compounds.
Ano: 1985 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3198
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Trace metals in the eastern part of the North Sea: 1: Analyses and short-term distributions OMA
Baeyens, W.F.J.; Gillain, G.; Decadt, G.; Elskens, I..
Advanced analysis procedures for dissolved and particulate trace metals in sea water have been developed and tested in international intercalibration exercises. Since these tests gave evidence that reliable data could be produced with such methods, trace metal distributions in the coastal waters of the eastern North Sea were studied.The spatial distributions of most dissolved and particulate trace metals are, at least qualitatively, similar. Their concentrations decrease with distance from the coast and the mouth of the Scheldt estuary ( particulates much stronger than dissolved species). The salinity gradient is similar (but opposite) to the trace metals and turbidity gradients. The five trace metals studied can be subdivided into two groups on the basis...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Analytical techniques Coastal zone Dissolved chemicals Quantitative distribution Salinity Suspended particulate matter Trace metals Turbidity ANE; North Sea.
Ano: 1987 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3284
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Trace metals in the eastern part of the North Sea: 2. Flows of Cd, Cu, Hg, Pb and Zn through the coastal area OMA
Baeyens, W.F.J.; Gillain, G.; Ronday, F.; Dehairs, F.A..
The residual flow lines of the Belgian coast are more or less parallel to the coast except in the area where the northeasterly flowing watermass coming from the Channel encounters the southwesterly-oriented Scheldt outflow. The result is a residual hydrodynamical front with, at the northern side, a less saline estuarine watermass, and at the southern side a more saline marine watermass. From the steady-state salinity pattern, diffusion coefficients perpendicular to the residual flow were deduced; they ranged from 21 to 108 m².s<sup>-1</sup>.The steady-state profiles of dissolved metals versus salinity indicate a dilution effect in the coastal-estuarine watermass and almost constant concentration in the marine watermass. Offshore fluxes of Cd,...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Coastal zone Trace metals ANE; North Sea.
Ano: 1987 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3156
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Tight coupling between enrichment of iron and manganese in North Sea suspended matter and sedimentary redox processes: evidence for seasonal variability OMA
Dehairs, F.A.; Baeyens, W.F.J.; Van Gansbeke, D..
Suspended matter and sediments from the North Sea were analysed for Al, Fe and Mn. A seasonal variation of Mn and Fe over Al ratios is observed. For most of the year suspended matter is enriched in Mn and Fe relative to average soil composition. No enrichment, and even depletion, occurs during a short period of the year (April-May) coinciding with the occurrence of the spring phytoplankton bloom. Surface sediments from the Southern Bight show the inverse image, with Mn and Fe enrichment occurring only in April-May and no enrichment during the rest of the year. These observations suggest a tight coupling between: (1) the change of redox potential in surface sediments, as triggered by the advection of organic matter from the spring bloom; (2) the outflow of...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Ferromanganese oxides Iron compounds Manganese compounds Redox reactions Seasonal variations Sediment chemistry Suspended load ANE; North Sea.
Ano: 1989 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3010
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Improvement of the semiautomated headspace analysis method for the determination of methylmercury in biological samples OMA
Lansens, P.; Baeyens, W.F.J..
An improvement in the extraction step in the method of Decadt et al. for determining methylmercury in biological tissues is described. The methylmercury is released from the tissue by use of sulphuric acid as the cleaving agent and immediately converted to the iodide form by iodoacetic acid. These reaction steps take place in a closed headspace vial. The methylmercury iodide is then headspace-injected into a gas-chromatograph and detected with a microwave-induced plasma detector. Quantitation is accomplished by standard addition. Analysis of one sample takes less than 15 min. The detection limit of the method is 20 ng methylmercury per gram biological tissue when 50 mg of tissue are taken.
Tipo: Info:eu-repo/semantics/article
Ano: 1990 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3091
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Determination of methylmercury in natural waters by headspace gas chromatography with microwave-induced plasma detection after preconcentration on a resin containing dithiocarbamate groups OMA
Lansens, P.; Meuleman, C.; Leermakers, M.; Baeyens, W.F.J..
A method for the determination of methylmercury at ng 1<sup>-1</sup> levels in natural waters is described. Methylmercury present in a sample is first preconcentrated on a column of a resin containing dithiocarbamate groups and eluted quantitatively with acidic thiourea solution. Methylmercury in the effluent is then converted to the iodide by addition of sulphuric acid and iodoacetic acid and determined by headspace gas chromatography with microwave-induced plasma detection. The adsorption properties of the resin are discussed.
Tipo: Info:eu-repo/semantics/article
Ano: 1990 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3092
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Behaviour of heavy metals in a mud flat of the Scheldt estuary, Belgium OMA
Panutrakul, S.; Baeyens, W.F.J..
The Ballasplaat intertidal mud flat in the Scheldt estuary has been polluted by Cd and Pb and also high amounts of organic matter as a result of suspended matter deposition. The degree of pollution is, however, not uniform over the mud flat due to varying physico-chemical conditions (essentially variable redox profiles). Measurements of the redox profile, and the metal concentrations in the pore water, the total sediment and the fraction <63 µm combined with sequential extraction results and enrichment factors can explain the behaviour of Cd, Pb, Fe and Mn in the sediments. In a strong anoxic sediment, where sulphate reducing bacteria are active, the heavy metals are trapped as poorly soluble metal complexes while in an oxic or suboxic sediment metals...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Cadmium Chemical reactions Estuaries Iron Lead Manganese Marine pollution Mud flats Physicochemical properties Sediment chemistry Sediment pollution Sediments ANE; Netherlands; Westerschelde; Ballastplaat.
Ano: 1991 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3112
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Particulate trace metals above the Southern Bight of the North Sea: 1. Analytical procedures and average aerosol concentrations OMA
Baeyens, W.F.J.; Dedeurwaerder, H..
Heavy metal concentrations in total particulate suspended matter and size fractionated particulate suspended matter above the Southern Bight of the North Sea have been assessed. Most of the samples were collected from a light vessel; the total sampling period covered about 70 days at sea. Stringent precautions were taken during sampling, storage, handling and analysis of the samples. As a conclusion, we found that on a long-term basis the aerosol concentrations above the North Sea have a fairly homogeneous composition, but short-term variations probably resulting from point emissions were observed. The cascade impactor results indicated that Pb, Cu, Cd and Zu were carried by submicrometer aerosols, Na, Fe, Mn and Al by supermicrometer aerosols. Most of the...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Aerosols Air pollution Atmospheric particulates Meteorology Seasonal variations Statistical analysis Trace metals Troposphere Winds ANE; North Sea; Southern Bight.
Ano: 1991 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3106
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Particulate trace metals above the Southern Bight of the North Sea: 2. Origin and behaviour of the trace metals OMA
Baeyens, W.F.J.; Dedeurwaerder, H..
Ninety-six aerosol samples were collected in all seasons and wind conditions in the troposphere of the Southern Bight of the North Sea. About one third of these samples were collected with a six stage cascade impactor sampler. Considering that in each sample metals were analyzed, the data set we had to handle consisted of about 2000 results. In addition, wind directions and wind speeds are also included in this data set. To interpret all these results, we relied upon two methods: (1) enrichment factors were calculated and allowed us to identify some of the metal sources; (2) three factors resulted from a multivariate analysis method: in the first factor we only find Na, representing the marine component; the second factor includes Al (a crustal and...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Aerosols Air pollution Atmospheric particulates Meteorology Seasonal variations Statistical analysis Trace metals Troposphere Winds ANE; North Sea; Southern Bight.
Ano: 1991 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3109
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Ammonium regeneration in the Scotia-Weddell Confluence area during spring 1988 OMA
Goeyens, L.; Tréguer, P.; Lancelot, C.; Mathot, S.; Becquevort, S.; Morvan, J.; Dehairs, F.A.; Baeyens, W.F.J..
Tipo: Info:eu-repo/semantics/article
Ano: 1991 URL: http://www.vliz.be/imisdocs/publications/279128.pdf
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Accumulation of suspended barite at mesopelagic depths and export production in the Southern Ocean OMA
Dehairs, F.A.; Baeyens, W.F.J.; Goeyens, L..
Tipo: Info:eu-repo/semantics/article
Ano: 1992 URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=10162
Registros recuperados: 32
Primeira ... 12 ... Última
 

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